緩凝劑的效果如下:
The effect of retarder is as follows:
1)降低半水石膏的溶解度;
1) Decrease the solubility of hemihydrate gypsum;
2)減緩半水化石膏的溶解速度;
2) slowing down the dissolution rate of hemihydrated gypsum;
3)吸附結(jié)晶石膏二水化物晶體表面的離子射亏,并將其結(jié)合到晶格中;
3) Adsorb the ions on the crystal surface of crystalline gypsum dihydrate and combine them into the lattice.
4)形成絡(luò)合物命斧,限制離子向二水石膏晶體附近擴(kuò)散田晚。
4) Formation of complexes to restrict ion diffusion near dihydrate gypsum crystals.
常用緩凝劑主要有:堿性磷酸鹽和磷酸銨、有機(jī)酸及其可溶性鹽(如檸檬酸和檸檬酸鹽)国葬、受損蛋白等贤徒。
Commonly used retarders are alkaline phosphate and ammonium phosphate, organic acid and its soluble salts (such as citric acid and citrate), damaged protein, etc.
學(xué)者們對(duì)幾種緩凝劑進(jìn)行了測(cè)試,結(jié)果表明汇四,緩凝劑的緩凝效果按如下順序增加接奈。結(jié)果表明,在初始凝固時(shí)結(jié)晶較粗通孽、較短序宦,硬化強(qiáng)度低于純水。
Scholars have tested several retarders. The results show that the retarding effect of retarders increases in the following order. The results show that the initial solidification crystallization is coarser and shorter, and the hardening strength is lower than that of pure water.
學(xué)者等研究了蔗糖對(duì)巴黎石膏凝固過(guò)程的影響利虫,發(fā)現(xiàn)當(dāng)Ca(OH)2同時(shí)存在時(shí)挨厚,蔗糖對(duì)巴黎石膏具有明顯的緩凝作用,認(rèn)為這可以用吸附理論來(lái)解釋舔远。
Scholars have studied the effect of sucrose on the solidification process of Paris gypsum, and found that when Ca (OH) 2 exists at the same time, sucrose has obvious retarding effect on Paris gypsum, which can be explained by adsorption theory.
關(guān)于檸檬酸和檸檬酸鈉的延緩作用弓席,專家認(rèn)為檸檬酸具有延緩作用。加入少量(小于0.1%)陌贾,有輕微的緩速效果转是,強(qiáng)度略有降低。當(dāng)摻量增加(超過(guò)0.2%)時(shí)矢盾,會(huì)嚴(yán)重影響二水石膏晶體的形成習(xí)慣粤段,使晶體不能相互生長(zhǎng)和連接。石膏漿即使完全水化,也不會(huì)凝結(jié)幢剂。
As for the delaying effect of citric acid and sodium citrate, experts believe that citric acid has delaying effect. Adding a small amount (less than 0.1%) has a slight slow-down effect and a slight decrease in strength. When the content increases (more than 0.2%), the formation habit of dihydrate gypsum crystals will be seriously affected, so that the crystals can not grow and connect with each other. Gypsum slurry will not coagulate even if it is completely hydrated.

學(xué)者們研究了檸檬酸鈉對(duì)巴黎石膏凝固的影響智贰,發(fā)現(xiàn)檸檬酸鈉在含量大于0.1%時(shí)具有較強(qiáng)的緩凝作用,降低了硬化漿體的強(qiáng)度凳赃。但當(dāng)摻量低于0.05%時(shí)涣母,具有促進(jìn)凝固的作用,硬化強(qiáng)度高于純水撕贞。他們認(rèn)為這是因?yàn)樵跐舛瘸^(guò)0.1%時(shí)更耻,由于冷凝時(shí)間長(zhǎng),晶體完全長(zhǎng)大捏膨,并且它具有促進(jìn)結(jié)晶生長(zhǎng)的作用秧均,所以結(jié)晶體的形成,硬化強(qiáng)度降低号涯。但在低濃度下目胡,情況正好相反,就像在水中一樣诚隙,會(huì)產(chǎn)生細(xì)小的針狀晶體讶隐。
Scholars have studied the effect of sodium citrate on the solidification of Paris gypsum, and found that sodium citrate has a strong retarding effect when the content of sodium citrate is more than 0.1%, which reduces the strength of hardened paste. But when the dosage is less than 0.05%, it can promote the solidification, and the hardening strength is higher than that of pure water. They think that the reason is that when the concentration exceeds 0.1%, because of the long time of condensation, the crystal grows completely, and it has the effect of promoting crystal growth, so the formation of crystals and the hardening strength decrease. At low concentrations, however, the opposite is true, as in water, where fine needle-like crystals are produced.
混凝劑溫和的凝血機(jī)制往往由于各種原因變得非常復(fù)雜,有時(shí)超出摻合料的佳用量本身會(huì)產(chǎn)生相反的效果,有時(shí)兩個(gè)或更多外面的另一個(gè)復(fù)合混合了反效果,除了進(jìn)一步的研究在理論上,這些問(wèn)題取決于積累經(jīng)驗(yàn)在生產(chǎn)實(shí)踐的過(guò)程中,選擇合適的劑量的添加劑品種和選擇好的起胰。
The mild coagulation mechanism of coagulant often becomes very complicated for various reasons. Sometimes the best dosage of coagulant will produce the opposite effect. Sometimes the compound of two or more outside will mix the opposite effect. In addition to further research, these problems depend on the selection of the most appropriate dosage of additives in the process of production and practice. Choose the best.